H3Sn anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

H3Sn- + Hydrogen cation = H4Sn

By formula: H3Sn- + H+ = H4Sn

Quantity Value Units Method Reference Comment
Δr350.5 ± 2.1kcal/molG+TSGal, Decouzon, et al., 2001gas phase
Δr349.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiH2; ; ΔS(EA)=10.0
Quantity Value Units Method Reference Comment
Δr342.3 ± 2.0kcal/molIMREGal, Decouzon, et al., 2001gas phase
Δr341.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiH2; ; ΔS(EA)=10.0

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Reference Comment
1.79163Check, Faust, et al., 2001NiH2; ; ΔS(EA)=10.0

Protonation reactions

H3Sn- + Hydrogen cation = H4Sn

By formula: H3Sn- + H+ = H4Sn

Quantity Value Units Method Reference Comment
Δr350.5 ± 2.1kcal/molG+TSGal, Decouzon, et al., 2001gas phase
Δr349.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiH2; ; ΔS(EA)=10.0
Quantity Value Units Method Reference Comment
Δr342.3 ± 2.0kcal/molIMREGal, Decouzon, et al., 2001gas phase
Δr341.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiH2; ; ΔS(EA)=10.0

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]


Notes

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