naphthalen-3-yl-2-ide anion
- Formula: C10H6-
- Molecular weight: 126.1552
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C10H6- + =
By formula: C10H6- + H+ = C10H7
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 377.0 ± 3.1 | kcal/mol | G+TS | Reed, Hare, et al., 2000 | gas phase; Between tBuOD and 1-pentyne |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 369.3 ± 3.0 | kcal/mol | IMRB | Reed, Hare, et al., 2000 | gas phase; Between tBuOD and 1-pentyne |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.60 ± 0.11 | IMRB | Reed, Hare, et al., 2000 | Between F5-pyridine and CS2 |
Protonation reactions
C10H6- + =
By formula: C10H6- + H+ = C10H7
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 377.0 ± 3.1 | kcal/mol | G+TS | Reed, Hare, et al., 2000 | gas phase; Between tBuOD and 1-pentyne |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 369.3 ± 3.0 | kcal/mol | IMRB | Reed, Hare, et al., 2000 | gas phase; Between tBuOD and 1-pentyne |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reed, Hare, et al., 2000
Reed, D.R.; Hare, M.; Kass, S.R.,
Formation of gas-phase dianions and distonic ions as a general method for the synthesis of protected reactive intermediates. Energetics of 2,3-and 2,6-dehydronaphthalene,
J. Am. Chem. Soc., 2000, 122, 43, 10689-10696, https://doi.org/10.1021/ja002351j
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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