pMe-C6H4S(O)(=NSO2CF3)NH anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H8F3N2O3S2- + Hydrogen cation = C8H9F3N2O3S2

By formula: C8H8F3N2O3S2- + H+ = C8H9F3N2O3S2

Quantity Value Units Method Reference Comment
Δr310.4 ± 2.0kcal/molIMREKoppel, Koppel, et al., 2001gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C8H8F3N2O3S2- + Hydrogen cation = C8H9F3N2O3S2

By formula: C8H8F3N2O3S2- + H+ = C8H9F3N2O3S2

Quantity Value Units Method Reference Comment
Δr310.4 ± 2.0kcal/molIMREKoppel, Koppel, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Koppel, et al., 2001
Koppel, I.A.; Koppel, J.; Leito, I.; Koppel, I.; Mishima, M.; Yagupolskii, L.M., The enormous acidifying effect of the supersubstituent =NSO2CF3 on the acidity of derivatives of benzenesulfonamide and toluene-p-sulfonamide in the gas phase and in dimethyl sulfoxide, J. Chem. Soc. Perkin Trans., 2001, 2, 2, 229-232, https://doi.org/10.1039/b005765g . [all data]


Notes

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