Methylamine, protonated
- Formula: CH6N+
- Molecular weight: 32.0645
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 57
- Options:
Reaction thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2H2O) + H2O = (CH6N+ • 3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.3 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 12.4 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 12.4 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.4 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.4 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.2 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • H2O) + H2O = (CH6N+ • 2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.6 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 14.6 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 14.6 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.5 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H2O = (CH6N+ • H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.8 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 18.8 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 18.8 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.8 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.3 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.3 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 10.7 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H4O2 = (CH6N+ • C2H4O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 21.4 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 24. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.3 | 459. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
(CH6N+ • 4) +
= (CH6N+ • 5
)
By formula: (CH6N+ • 4H2O) + H2O = (CH6N+ • 5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.4 | cal/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 3.5 | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
(CH6N+ • 5) +
= (CH6N+ • 6
)
By formula: (CH6N+ • 5H2O) + H2O = (CH6N+ • 6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 8.5 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.9 | cal/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 3.1 | 259. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O2 = (CH6N+ • C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 12.5 | 461. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H5F3O2 = (CH6N+ • C4H5F3O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.4 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 9.4 | 450. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.6 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.9 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.0 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H8O = (CH6N+ • C4H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.4 | 553. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O = (CH6N+ • C5H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.9 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.8 | 549. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.3 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 8.9 | 496. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3HN = (CH6N+ • C3HN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.6 | 500. | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
(CH6N+ • 2) +
= (CH6N+ •
• 2
)
By formula: (CH6N+ • 2C2H3N) + CH4S = (CH6N+ • CH4S • 2C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.8 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20. | cal/mol*K | N/A | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 2.4 | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2CH5N) + CH5N = (CH6N+ • 3CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 17.0 | kcal/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 41.6 | cal/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • CH5N) + CH5N = (CH6N+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 19.2 | kcal/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.9 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 39.9 | cal/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H12O2 = (CH6N+ • C5H12O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 31.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 31.2 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 32.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 32.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C8H18O = (CH6N+ • C8H18O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 25.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 28.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 28.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 25.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + C12H22O = (CH6N+ • C12H22O)
By formula: CH6N+ + C12H22O = (CH6N+ • C12H22O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 27.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 31.4 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H2S = (CH6N+ • H2S)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.8 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 5.4 | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH5N = (CH6N+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.4 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 21.7 | kcal/mol | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.3 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 23.6 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H7N = (CH6N+ • C4H7N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.1 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27. | cal/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O2 = (CH6N+ • C4H10O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.1 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H11NO3 = (CH6N+ • C6H11NO3)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 40.1 | kcal/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.1 | cal/mol*K | PHPMS | Meot-Ner, 1984, 2 | gas phase |
(CH6N+ • 3) +
= (CH6N+ • 4
)
By formula: (CH6N+ • 3H2O) + H2O = (CH6N+ • 4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.3 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O2 = (CH6N+ • C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H14O = (CH6N+ • C6H14O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 29.3 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C8H16O2 = (CH6N+ • C8H16O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 34.8 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H12O = (CH6N+ • C6H12O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 27.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH2O2 = (CH6N+ • CH2O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH4O = (CH6N+ • CH4O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H6O = (CH6N+ • C3H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H8O = (CH6N+ • C3H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.6 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3NO2 = (CH6N+ • CH3NO2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H3F3O = (CH6N+ • C2H3F3O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 28.5 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H3N = (CH6N+ • H3N)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.4 | kcal/mol | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H6O2 = (CH6N+ • C3H6O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.8 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3NO = (CH6N+ • CH3NO)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
(CH6N+ • ) +
= (CH6N+ •
•
)
By formula: (CH6N+ • C2H3N) + CH4S = (CH6N+ • CH4S • C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.9 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2C2H3N) + C2H3N = (CH6N+ • 3C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • C2H3N) + C2H3N = (CH6N+ • 2C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18.6 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C7H5N = (CH6N+ • C7H5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 29.4 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 31.2 | cal/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
(CH6N+ • 3) +
= (CH6N+ • 4
)
By formula: (CH6N+ • 3CH5N) + CH5N = (CH6N+ • 4CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.8 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.5 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H5N = (CH6N+ • C4H5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18.6 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H10 = (CH6N+ • C6H10)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.6 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 16.9 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CHN = (CH6N+ • CHN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.8 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.9 | cal/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH4S = (CH6N+ • CH4S)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CHN = (CH6N+ • CHN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.8 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.9 | cal/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH2O2 = (CH6N+ • CH2O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3Br = (CH6N+ • CH3Br)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3Cl = (CH6N+ • CH3Cl)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.7 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.6 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3F = (CH6N+ • CH3F)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.8 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.3 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3NO = (CH6N+ • CH3NO)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH3NO2 = (CH6N+ • CH3NO2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 20.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH4O = (CH6N+ • CH4O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH4S = (CH6N+ • CH4S)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CH5N = (CH6N+ • CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.4 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 21.7 | kcal/mol | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.3 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 23.6 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • CH5N) + CH5N = (CH6N+ • 2CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 19.2 | kcal/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.9 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 39.9 | cal/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2CH5N) + CH5N = (CH6N+ • 3CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 17.0 | kcal/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 41.6 | cal/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
(CH6N+ • 3) +
= (CH6N+ • 4
)
By formula: (CH6N+ • 3CH5N) + CH5N = (CH6N+ • 4CH5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.8 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.5 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + CO2 = (CH6N+ • CO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.2 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1978 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.4 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1978 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H3F3O = (CH6N+ • C2H3F3O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 28.5 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H3N = (CH6N+ • C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.2 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.7 | cal/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
(CH6N+ • ) +
= (CH6N+ •
•
)
By formula: (CH6N+ • C2H3N) + CH4S = (CH6N+ • CH4S • C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.9 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
(CH6N+ • 2) +
= (CH6N+ •
• 2
)
By formula: (CH6N+ • 2C2H3N) + CH4S = (CH6N+ • CH4S • 2C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 7.8 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20. | cal/mol*K | N/A | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 2.4 | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • C2H3N) + C2H3N = (CH6N+ • 2C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18.6 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2C2H3N) + C2H3N = (CH6N+ • 3C2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H4O2 = (CH6N+ • C2H4O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 21.4 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.3 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 24. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.3 | 459. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.3 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 8.9 | 496. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 29.3 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C2H6S = (CH6N+ • C2H6S)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.6 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 19.6 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3HN = (CH6N+ • C3HN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.6 | 500. | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H6O = (CH6N+ • C3H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H6O2 = (CH6N+ • C3H6O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.8 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C3H8O = (CH6N+ • C3H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.6 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H5F3O2 = (CH6N+ • C4H5F3O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.4 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 9.4 | 450. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H5N = (CH6N+ • C4H5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18.6 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.0 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H7N = (CH6N+ • C4H7N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.1 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27. | cal/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H8O = (CH6N+ • C4H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.4 | 553. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 22.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 25.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.6 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.9 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 10.0 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C4H10O2 = (CH6N+ • C4H10O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.1 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 30.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O = (CH6N+ • C5H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.9 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 11.8 | 549. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O2 = (CH6N+ • C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.2 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H10O2 = (CH6N+ • C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 12.5 | 461. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C5H12O2 = (CH6N+ • C5H12O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 31.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 31.2 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 32.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 32.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H6 = (CH6N+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 18.8 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.1 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H10 = (CH6N+ • C6H10)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 11.6 | kcal/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 16.9 | cal/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H11NO3 = (CH6N+ • C6H11NO3)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 40.1 | kcal/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.1 | cal/mol*K | PHPMS | Meot-Ner, 1984, 2 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H12O = (CH6N+ • C6H12O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 27.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C6H14O = (CH6N+ • C6H14O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 24.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C7H5N = (CH6N+ • C7H5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 29.4 | kcal/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 31.2 | cal/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C8H16O2 = (CH6N+ • C8H16O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 30.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 34.8 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + C8H18O = (CH6N+ • C8H18O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.0 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrH° | 25.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 28.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
| ΔrS° | 28.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + C12H22O = (CH6N+ • C12H22O)
By formula: CH6N+ + C12H22O = (CH6N+ • C12H22O)
Bond type: Hydrogen bonds of the type NH+-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 27.2 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 31.4 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H2O = (CH6N+ • H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.8 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 18.8 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 18.8 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 21.8 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.3 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.3 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 10.7 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
(CH6N+ • ) +
= (CH6N+ • 2
)
By formula: (CH6N+ • H2O) + H2O = (CH6N+ • 2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.6 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 14.6 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 14.6 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.2 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.7 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 7.5 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
(CH6N+ • 2) +
= (CH6N+ • 3
)
By formula: (CH6N+ • 2H2O) + H2O = (CH6N+ • 3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.3 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrH° | 12.4 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrH° | 12.4 | kcal/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.1 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| ΔrS° | 26.4 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| ΔrS° | 26.4 | cal/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 5.2 | kcal/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
(CH6N+ • 3) +
= (CH6N+ • 4
)
By formula: (CH6N+ • 3H2O) + H2O = (CH6N+ • 4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.3 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.0 | cal/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
(CH6N+ • 4) +
= (CH6N+ • 5
)
By formula: (CH6N+ • 4H2O) + H2O = (CH6N+ • 5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.0 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.4 | cal/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 3.5 | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
(CH6N+ • 5) +
= (CH6N+ • 6
)
By formula: (CH6N+ • 5H2O) + H2O = (CH6N+ • 6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 8.5 | kcal/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20.9 | cal/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 3.1 | 259. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H2S = (CH6N+ • H2S)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.8 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 20. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 5.4 | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
CH6N+ + = (CH6N+ •
)
By formula: CH6N+ + H3N = (CH6N+ • H3N)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 21.4 | kcal/mol | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26. | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration,
J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016
. [all data]
Lau and Kebarle, 1981
Lau, Y.K.; Kebarle, P.,
Hydrogen Bonding Solvent Effect on the Basicity of Primary Amines CH3NH2, C2H5NH2, AND CF3CH2NH2,
Can. J. Chem., 1981, 59, 1, 151, https://doi.org/10.1139/v81-024
. [all data]
Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V.,
Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions,
J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543
. [all data]
Meot-Ner, 1984
Meot-Ner, (Mautner)M.,
The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects,
J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015
. [all data]
Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites,
J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020
. [all data]
Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W.,
The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters,
J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021
. [all data]
Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M.,
Intermolecular Forces in Organic Clusters,
J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024
. [all data]
Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W.,
The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes,
J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497
. [all data]
Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers,
J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012
. [all data]
Yamdagni and Kebarle, 1973
Yamdagni, R.; Kebarle, P.,
Gas - Phase Basicites of Amines. Hydrogen Bonding in Proton - Bound Amine Dimers and Proton - Induced Cyclization of alpha, omega - Diamines,
J. Am. Chem. Soc., 1973, 95, 11, 3504, https://doi.org/10.1021/ja00792a010
. [all data]
Meot-Ner, 1984, 2
Meot-Ner, (Mautner),
The Ionic Hydrogen Bond. 4. Intramolecular and Multiple Bonds. Proton Affinities, Hydration and Complexes of Amides and Amino Acid Derivatives,
J. Am. Chem. Soc., 1984, 106, 2, 278, https://doi.org/10.1021/ja00314a003
. [all data]
Yamdagni and Kebarle, 1974
Yamdagni, R.; Kebarle, P.,
The hydrogen bond energies in ClHCl- and Cl-(HCl)n,
Can. J. Chem., 1974, 52, 2449. [all data]
Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M.,
Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives,
J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034
. [all data]
Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M.,
Ion - Molecule Condensation Reactions: A Mechanism for Chemical Synthesis in Ionized Reducing Planetary Atmospheres,
Origins Life, 1978, 9, 2, 115, https://doi.org/10.1007/BF00931409
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.