Methyl chloride, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CH4Cl+ • Chloromethane) + Chloromethane = (CH4Cl+ • 2Chloromethane)

By formula: (CH4Cl+ • CH3Cl) + CH3Cl = (CH4Cl+ • 2CH3Cl)

Quantity Value Units Method Reference Comment
Δr4.2kcal/molHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable
Quantity Value Units Method Reference Comment
Δr1.1cal/mol*KHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.0182.HPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CH4Cl+ • Chloromethane) + Chloromethane = (CH4Cl+ • 2Chloromethane)

By formula: (CH4Cl+ • CH3Cl) + CH3Cl = (CH4Cl+ • 2CH3Cl)

Quantity Value Units Method Reference Comment
Δr4.2kcal/molHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable
Quantity Value Units Method Reference Comment
Δr1.1cal/mol*KHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.0182.HPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Luczynski, Malicki, et al., 1974
Luczynski, Z.; Malicki, W.; Wincel, H., Positive Ion Reactions of Methyl Cloride in the Gas Phase, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 3, 321, https://doi.org/10.1016/0020-7381(74)85009-6 . [all data]


Notes

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