Methanone, dicyclopropyl-, protonated

• Formula: C₇H₁₁O⁺
• Molecular weight: 111.1611
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
• Options:
  • Switch to SI units

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C₇H₁₁O⁺ • 3) +  = (C₇H₁₁O⁺ • 4)

By formula: (C₇H₁₁O⁺ • 3H₂O) + H₂O = (C₇H₁₁O⁺ • 4H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

(C₇H₁₁O⁺ • 2) +  = (C₇H₁₁O⁺ • 3)

By formula: (C₇H₁₁O⁺ • 2H₂O) + H₂O = (C₇H₁₁O⁺ • 3H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • ) +  = (C₇H₁₁O⁺ • 2)

By formula: (C₇H₁₁O⁺ • H₂O) + H₂O = (C₇H₁₁O⁺ • 2H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + H₂O = (C₇H₁₁O⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + CHN = (C₇H₁₁O⁺ • CHN)

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + C₂H₃N = (C₇H₁₁O⁺ • C₂H₃N)

Free energy of reaction

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + CHN = (C₇H₁₁O⁺ • CHN)

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + C₂H₃N = (C₇H₁₁O⁺ • C₂H₃N)

Free energy of reaction

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + H₂O = (C₇H₁₁O⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • ) +  = (C₇H₁₁O⁺ • 2)

By formula: (C₇H₁₁O⁺ • H₂O) + H₂O = (C₇H₁₁O⁺ • 2H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • 2) +  = (C₇H₁₁O⁺ • 3)

By formula: (C₇H₁₁O⁺ • 2H₂O) + H₂O = (C₇H₁₁O⁺ • 3H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • 3) +  = (C₇H₁₁O⁺ • 4)

By formula: (C₇H₁₁O⁺ • 3H₂O) + H₂O = (C₇H₁₁O⁺ • 4H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Bromilow, Abboud, et al., 1980
Bromilow, J.; Abboud, J.L.M.; Lebrilla, C.B.; Taft, R.W.; Scorrano, G.; Lucchini, V., Oxonium Ions. Solvation by Single Acetonitrile Molecules in the Gas Phase and by Bulk Solvents, J. Am. Chem. Soc., 1980, 103, 18, 5448, https://doi.org/10.1021/ja00408a028 . [all data]

Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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