tert-Butyl, positive ion

• Formula: C₄H₉⁺
• Molecular weight: 57.1137
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + H₃N = (C₄H₉⁺ • H₃N)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₇H₈ = (C₄H₉⁺ • C₇H₈)

(C₄H₉⁺ • 3) +  = (C₄H₉⁺ • 4)

By formula: (C₄H₉⁺ • 3H₂O) + H₂O = (C₄H₉⁺ • 4H₂O)

(C₄H₉⁺ • 2) +  = (C₄H₉⁺ • 3)

By formula: (C₄H₉⁺ • 2H₂O) + H₂O = (C₄H₉⁺ • 3H₂O)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₆H₆ = (C₄H₉⁺ • C₆H₆)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHN = (C₄H₉⁺ • CHN)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₂H₆S = (C₄H₉⁺ • C₂H₆S)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + F₂O₂S = (C₄H₉⁺ • F₂O₂S)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHCl₃ = (C₄H₉⁺ • CHCl₃)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₃Cl = (C₄H₉⁺ • CH₃Cl)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₃H₈ = (C₄H₉⁺ • C₃H₈)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₂H₅Cl = (C₄H₉⁺ • C₂H₅Cl)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₂Cl₂ = (C₄H₉⁺ • CH₂Cl₂)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHF₃ = (C₄H₉⁺ • CHF₃)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CF₄ = (C₄H₉⁺ • CF₄)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + H₂O = (C₄H₉⁺ • H₂O)

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CF₄ = (C₄H₉⁺ • CF₄)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHCl₃ = (C₄H₉⁺ • CHCl₃)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHF₃ = (C₄H₉⁺ • CHF₃)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CHN = (C₄H₉⁺ • CHN)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₂Cl₂ = (C₄H₉⁺ • CH₂Cl₂)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₃Cl = (C₄H₉⁺ • CH₃Cl)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₂H₅Cl = (C₄H₉⁺ • C₂H₅Cl)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₂H₆S = (C₄H₉⁺ • C₂H₆S)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₃H₈ = (C₄H₉⁺ • C₃H₈)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₆H₆ = (C₄H₉⁺ • C₆H₆)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + C₇H₈ = (C₄H₉⁺ • C₇H₈)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + F₂O₂S = (C₄H₉⁺ • F₂O₂S)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + H₂O = (C₄H₉⁺ • H₂O)

(C₄H₉⁺ • 2) +  = (C₄H₉⁺ • 3)

By formula: (C₄H₉⁺ • 2H₂O) + H₂O = (C₄H₉⁺ • 3H₂O)

(C₄H₉⁺ • 3) +  = (C₄H₉⁺ • 4)

By formula: (C₄H₉⁺ • 3H₂O) + H₂O = (C₄H₉⁺ • 4H₂O)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + H₃N = (C₄H₉⁺ • H₃N)

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Szulejko and McMahon, 1991
Szulejko, J.E.; McMahon, T.B., A Pulsed Electron Beam, Variable Temperature, High Pressure Mass Spectrometric Reevaluation of the Proton Affinity Difference Between 2-Methylpropene and Ammonia, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 279, https://doi.org/10.1016/0168-1176(91)85109-Y . [all data]

Meot-Ner (Mautner) and Sieck, 1990
Meot-Ner (Mautner), M.; Sieck, L.W., Ion Thermochemistry at High Temperatures. 1. Thermochemistry of the Ammonium Ion from Variable - Temperature Equilibrium Measurements. Proton Transfer, Association, and Decomposition Reactions in Ammonia, Isobutene, and t-Butylamine, J. Phys. Chem., 1990, 94, 19, 7730, https://doi.org/10.1021/j100382a076 . [all data]

Stone and Stone, 1991
Stone, J.M.; Stone, J.A., A High Pressure Mass Spectrometric Study of the Binding of (CH3)3Si+ and (CH3)3C+ to Toluene and Benzene, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 247, https://doi.org/10.1016/0168-1176(91)85107-W . [all data]

Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P., Condensation Reactions Involving Carbonium Ions and Lewis Bases in the Gas Phase. Hydration of the t - Butyl Cation, J. Am. Chem., 1977, 99, 2, 360, https://doi.org/10.1021/ja00444a008 . [all data]

Hiraoka and Kebarle, 1977, 2
Hiraoka, K.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Proton in Hydrogen Sulfide and Hydrogen Sulfide - Water Mixtures. Stabilities of the Hydrogen Bonded Complexes H+(H2S)x(H2O)y, Can. J. Chem., 1977, 55, 1, 24, https://doi.org/10.1139/v77-005 . [all data]

Sen Sharma, Ikuta, et al., 1982
Sen Sharma, D.K.; Ikuta, S.; Kebarle, P., Alkylation of Benzene by Alkyl Cations. Stability of the tert - Butyl Benzenium Ion, Can. J. Chem., 1982, 60, 18, 2325, https://doi.org/10.1139/v82-331 . [all data]

Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M., Solvation of the Proton by HCN and CH3CN. Condensation of HCN with Ions in the Gas Phase., J. Am. Chem. Soc., 1978, 100, 15, 4694, https://doi.org/10.1021/ja00483a012 . [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]

Sunner, Hirao, et al., 1989
Sunner, J.A.; Hirao, K.; Kebarle, P., Hydride - Transfer Reactions. Temperature Dependence of Rate Constants for i-C3H7+ + HC(CH3)3 = C3H8 + C(CH3)3+. Clusters of i-C3H7+ and t-C4H9+ with Propane and Isobutane, J. Phys. Chem., 1989, 93, 10, 4010, https://doi.org/10.1021/j100347a030 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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