Tetramethylhydrazine, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C4H12N2+ + Tetramethylhydrazine = (C4H12N2+ • Tetramethylhydrazine)

By formula: C4H12N2+ + C4H12N2 = (C4H12N2+ • C4H12N2)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr13.0kcal/molPHPMSNelsen, Rumak, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Δr26.8cal/mol*KPHPMSNelsen, Rumak, et al., 1987gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nelsen, Rumak, et al., 1987
Nelsen, S.F.; Rumak, D.T.; Meot-Ner (Mautner), M., Kinetic effects of an unusually large neutral to radical cation geometry change. Slow electron transfer rections between alkylhydrazines, J. Am. Chem. Soc., 1987, 109, 5, 1373, https://doi.org/10.1021/ja00239a015 . [all data]


Notes

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