Tetramethylhydrazine, positive ion
- Formula: C4H12N2+
- Molecular weight: 88.1509
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
C4H12N2+ + = (C4H12N2+ •
)
By formula: C4H12N2+ + C4H12N2 = (C4H12N2+ • C4H12N2)
Bond type: Charge transfer bond (positive ion)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 54.4 | kJ/mol | PHPMS | Nelsen, Rumak, et al., 1987 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 112. | J/mol*K | PHPMS | Nelsen, Rumak, et al., 1987 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nelsen, Rumak, et al., 1987
Nelsen, S.F.; Rumak, D.T.; Meot-Ner (Mautner), M.,
Kinetic effects of an unusually large neutral to radical cation geometry change. Slow electron transfer rections between alkylhydrazines,
J. Am. Chem. Soc., 1987, 109, 5, 1373, https://doi.org/10.1021/ja00239a015
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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