1-Propanol, protonated
- Formula: C3H9O+
- Molecular weight: 61.1024
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Reaction thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C3H8O = (C3H9O+ • C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 127. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; switching reaction(CH3CNH+)CH3CN; Lias, Liebman, et al., 1984, Deakyne, Meot-Ner (Mautner), et al., 1986 |
| ΔrH° | 132. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 112. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; switching reaction(CH3CNH+)CH3CN; Lias, Liebman, et al., 1984, Deakyne, Meot-Ner (Mautner), et al., 1986 |
| ΔrS° | 126. | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 94.6 | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C2H6O = (C3H9O+ • C2H6O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 128. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 120. | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 92.0 | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
(C3H9O+ • 7) +
= (C3H9O+ • 8
)
By formula: (C3H9O+ • 7C3H8O) + C3H8O = (C3H9O+ • 8C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 130. | J/mol*K | N/A | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 17. | 215. | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
(C3H9O+ • 2) +
= (C3H9O+ • 3
)
By formula: (C3H9O+ • 2C3H8O) + C3H8O = (C3H9O+ • 3C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 60.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 59.4 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 107. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 99.6 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • 3) +
= (C3H9O+ • 4
)
By formula: (C3H9O+ • 3C3H8O) + C3H8O = (C3H9O+ • 4C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 49.0 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 96.2 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • ) +
= (C3H9O+ • 2
)
By formula: (C3H9O+ • C3H8O) + C3H8O = (C3H9O+ • 2C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 90.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 79.1 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 131. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 96.2 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • 2) +
= (C3H9O+ • 3
)
By formula: (C3H9O+ • 2H2O) + H2O = (C3H9O+ • 3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 54.4 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 102. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 3) +
= (C3H9O+ • 4
)
By formula: (C3H9O+ • 3H2O) + H2O = (C3H9O+ • 4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46.0 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 95.8 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 4) +
= (C3H9O+ • 5
)
By formula: (C3H9O+ • 4H2O) + H2O = (C3H9O+ • 5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 40. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 86.6 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 5) +
= (C3H9O+ • 6
)
By formula: (C3H9O+ • 5H2O) + H2O = (C3H9O+ • 6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 37. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 87.0 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • ) +
= (C3H9O+ • 2
)
By formula: (C3H9O+ • H2O) + H2O = (C3H9O+ • 2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 74.9 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 110. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 4) +
= (C3H9O+ • 5
)
By formula: (C3H9O+ • 4C3H8O) + C3H8O = (C3H9O+ • 5C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 45.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 106. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
(C3H9O+ • 5) +
= (C3H9O+ • 6
)
By formula: (C3H9O+ • 5C3H8O) + C3H8O = (C3H9O+ • 6C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 120. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
(C3H9O+ • 6) +
= (C3H9O+ • 7
)
By formula: (C3H9O+ • 6C3H8O) + C3H8O = (C3H9O+ • 7C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 45.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 128. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + H2O = (C3H9O+ • H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 100. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 117. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C2H3N = (C3H9O+ • C2H3N)
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 98.7 | 320. | ICR | Bromilow, Abboud, et al., 1980 | gas phase; switching reaction,n((CH3)2OH+)(CH3)2O; Grimsrud and Kebarle, 1973 |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C2H3N = (C3H9O+ • C2H3N)
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 98.7 | 320. | ICR | Bromilow, Abboud, et al., 1980 | gas phase; switching reaction,n((CH3)2OH+)(CH3)2O; Grimsrud and Kebarle, 1973 |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C2H6O = (C3H9O+ • C2H6O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 128. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 120. | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 92.0 | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + C3H8O = (C3H9O+ • C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 127. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; switching reaction(CH3CNH+)CH3CN; Lias, Liebman, et al., 1984, Deakyne, Meot-Ner (Mautner), et al., 1986 |
| ΔrH° | 132. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 112. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; switching reaction(CH3CNH+)CH3CN; Lias, Liebman, et al., 1984, Deakyne, Meot-Ner (Mautner), et al., 1986 |
| ΔrS° | 126. | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 94.6 | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986 |
(C3H9O+ • ) +
= (C3H9O+ • 2
)
By formula: (C3H9O+ • C3H8O) + C3H8O = (C3H9O+ • 2C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 90.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 79.1 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 131. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 96.2 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • 2) +
= (C3H9O+ • 3
)
By formula: (C3H9O+ • 2C3H8O) + C3H8O = (C3H9O+ • 3C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 60.2 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 59.4 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 107. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 99.6 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • 3) +
= (C3H9O+ • 4
)
By formula: (C3H9O+ • 3C3H8O) + C3H8O = (C3H9O+ • 4C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.8 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrH° | 49.0 | kJ/mol | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 104. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| ΔrS° | 96.2 | J/mol*K | PHPMS | Hiraoka, Morise, et al., 1986 | gas phase |
(C3H9O+ • 4) +
= (C3H9O+ • 5
)
By formula: (C3H9O+ • 4C3H8O) + C3H8O = (C3H9O+ • 5C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 45.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 106. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
(C3H9O+ • 5) +
= (C3H9O+ • 6
)
By formula: (C3H9O+ • 5C3H8O) + C3H8O = (C3H9O+ • 6C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46.4 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 120. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
(C3H9O+ • 6) +
= (C3H9O+ • 7
)
By formula: (C3H9O+ • 6C3H8O) + C3H8O = (C3H9O+ • 7C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 45.6 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 128. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
(C3H9O+ • 7) +
= (C3H9O+ • 8
)
By formula: (C3H9O+ • 7C3H8O) + C3H8O = (C3H9O+ • 8C3H8O)
Bond type: Hydrogen bonds of the type OH-O between organics
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 130. | J/mol*K | N/A | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
| ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 17. | 215. | PHPMS | Meot-Ner (Mautner), 1992 | gas phase; Entropy change calculated or estimated |
C3H9O+ + = (C3H9O+ •
)
By formula: C3H9O+ + H2O = (C3H9O+ • H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 100. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 117. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • ) +
= (C3H9O+ • 2
)
By formula: (C3H9O+ • H2O) + H2O = (C3H9O+ • 2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 74.9 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 110. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 2) +
= (C3H9O+ • 3
)
By formula: (C3H9O+ • 2H2O) + H2O = (C3H9O+ • 3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 54.4 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 102. | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 3) +
= (C3H9O+ • 4
)
By formula: (C3H9O+ • 3H2O) + H2O = (C3H9O+ • 4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 46.0 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 95.8 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 4) +
= (C3H9O+ • 5
)
By formula: (C3H9O+ • 4H2O) + H2O = (C3H9O+ • 5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 40. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 86.6 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
(C3H9O+ • 5) +
= (C3H9O+ • 6
)
By formula: (C3H9O+ • 5H2O) + H2O = (C3H9O+ • 6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 37. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 87.0 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M.,
Intermolecular Forces in Organic Clusters,
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Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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