Propionyl, positive ion
- Formula: C3H5O+
- Molecular weight: 57.0707
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
By formula: C3H5O+ + H2O = (C3H5O+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 99.2 | kJ/mol | PHPMS | Davidson, Meza-Hojer, et al., 1979 | gas phase; forms protonated propanoic acid |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 147. | J/mol*K | PHPMS | Davidson, Meza-Hojer, et al., 1979 | gas phase; forms protonated propanoic acid |
By formula: (C3H5O+ • 2H2O) + H2O = (C3H5O+ • 3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 68.6 | kJ/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase |
By formula: (C3H5O+ • 3H2O) + H2O = (C3H5O+ • 4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 53.1 | kJ/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Davidson, Meza-Hojer, et al., 1979
Davidson, W.R.; Meza-Hojer, S.; Kebarle, P.,
Gas Phase Ion Equilibria: RCO+ + OH2 ---> RC(OH)2+; Heats of Formation of Acylium Ions RCO+ and Protonated Acids RC(OH)2+; Gas Phase Catalysis of Proton Shift RC(OH)2+ ---> RCO(OH2)+,
Can. J. Chem., 1979, 57, 24, 3205, https://doi.org/10.1139/v79-525
. [all data]
Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P.,
Condensation reactions involving carbonium ions in the gas phase synthesis of protonated acids in gaseous methane containing carbon monoxide and water vapor,
J. Am. Chem. Soc., 1977, 99, 366. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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