CH2COCH3, positive ion

• Formula: C₃H₅O⁺
• Molecular weight: 57.0707
• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Ion clustering data
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C₃H₅O⁺ +  = (C₃H₅O⁺ • )

By formula: C₃H₅O⁺ + C₃H₈O = (C₃H₅O⁺ • C₃H₈O)

C₃H₅O⁺ +  = (C₃H₅O⁺ • )

By formula: C₃H₅O⁺ + C₂H₃N = (C₃H₅O⁺ • C₂H₃N)

Free energy of reaction

(C₃H₅O⁺ • 2) +  = (C₃H₅O⁺ • 3)

By formula: (C₃H₅O⁺ • 2H₂O) + H₂O = (C₃H₅O⁺ • 3H₂O)

(C₃H₅O⁺ • 3) +  = (C₃H₅O⁺ • 4)

By formula: (C₃H₅O⁺ • 3H₂O) + H₂O = (C₃H₅O⁺ • 4H₂O)

(C₃H₅O⁺ • ) +  = (C₃H₅O⁺ • 2)

By formula: (C₃H₅O⁺ • H₂O) + H₂O = (C₃H₅O⁺ • 2H₂O)

C₃H₅O⁺ +  = (C₃H₅O⁺ • )

By formula: C₃H₅O⁺ + H₂O = (C₃H₅O⁺ • H₂O)

C₃H₅O⁺ +  = (C₃H₅O⁺ • )

By formula: C₃H₅O⁺ + C₃H₆O = (C₃H₅O⁺ • C₃H₆O)

Free energy of reaction

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell, Rozeboom, et al., 1984
Caldwell, G.; Rozeboom, M.D.; Kiplinger, J.P.; Bartmess, J.E., Anion-alcohol hydrogen bond strengths in the gas phase, J. Am. Chem. Soc., 1984, 106, 4660. [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase, J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076 . [all data]

Meot-ner, 1988
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Mackay, Rakshit, et al., 1982
Mackay, G.I.; Rakshit, A.B.; Bohme, D.K., An Experimental Study of the Reactivity and Relative Basicity of the Methoxide Anion in the Gas Phase at Room Temperature, and their Perturbation by Methanol Solvent, Can. J. Chem., 1982, 60, 20, 2594, https://doi.org/10.1139/v82-373 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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