Propiolonitrile, protonated
- Formula: C3H2N+
- Molecular weight: 52.0541
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
C3H2N+ + = (C3H2N+ •
)
By formula: C3H2N+ + H2O = (C3H2N+ • H2O)
Bond type: Hydrogen bond (positive ion to hydride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 97.5 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 99.6 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
C3H2N+ + = (C3H2N+ •
)
By formula: C3H2N+ + C3HN = (C3H2N+ • C3HN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 115. | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 108. | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
C3H2N+ + = (C3H2N+ •
)
By formula: C3H2N+ + CHN = (C3H2N+ • CHN)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 99.6 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 107. | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites,
J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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