Dimethyl sulfide, protonated

• Formula: C₂H₇S⁺
• Molecular weight: 63.141
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₇S⁺ +  = (C₂H₇S⁺ • )

By formula: C₂H₇S⁺ + C₂H₆S = (C₂H₇S⁺ • C₂H₆S)

C₂H₇S⁺ +  = (C₂H₇S⁺ • )

By formula: C₂H₇S⁺ + H₂O = (C₂H₇S⁺ • H₂O)

(C₂H₇S⁺ • ) +  = (C₂H₇S⁺ • 2)

By formula: (C₂H₇S⁺ • H₂O) + H₂O = (C₂H₇S⁺ • 2H₂O)

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C₂H₇S⁺ +  = (C₂H₇S⁺ • )

By formula: C₂H₇S⁺ + C₂H₆S = (C₂H₇S⁺ • C₂H₆S)

C₂H₇S⁺ +  = (C₂H₇S⁺ • )

By formula: C₂H₇S⁺ + H₂O = (C₂H₇S⁺ • H₂O)

(C₂H₇S⁺ • ) +  = (C₂H₇S⁺ • 2)

By formula: (C₂H₇S⁺ • H₂O) + H₂O = (C₂H₇S⁺ • 2H₂O)

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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