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Dimethyl sulfide, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C2H7S+ + Dimethyl sulfide = (C2H7S+ bullet Dimethyl sulfide)

By formula: C2H7S+ + C2H6S = (C2H7S+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar110.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, inconsistent with other protonated sulfur dimers
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, inconsistent with other protonated sulfur dimers

C2H7S+ + Water = (C2H7S+ bullet Water)

By formula: C2H7S+ + H2O = (C2H7S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar50.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984
Deltar54.8kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(C2H7S+ bullet Water) + Water = (C2H7S+ bullet 2Water)

By formula: (C2H7S+ bullet H2O) + H2O = (C2H7S+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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