Dimethyl sulfide, positive ion
- Formula: C2H6S+
- Molecular weight: 62.133
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Clustering reactions
C2H6S+ + = (C2H6S+ •
)
By formula: C2H6S+ + C2H6S = (C2H6S+ • C2H6S)
Bond type: Charge transfer bond (positive ion)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 26.8 | kcal/mol | DT | Deng, Illies, et al., 1995 | gas phase; ΔrH(0K) = 27.6 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.5 | cal/mol*K | DT | Deng, Illies, et al., 1995 | gas phase; ΔrH(0K) = 27.6 kcal/mol |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M.,
A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment,
J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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