Ethanol, 2,2,2-trifluoro-, protonated

• Formula: C₂H₄F₃O⁺
• Molecular weight: 101.0472
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₄F₃O⁺ +  = (C₂H₄F₃O⁺ • )

By formula: C₂H₄F₃O⁺ + H₂O = (C₂H₄F₃O⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

C₂H₄F₃O⁺ +  = (C₂H₄F₃O⁺ • )

By formula: C₂H₄F₃O⁺ + C₂H₃F₃O = (C₂H₄F₃O⁺ • C₂H₃F₃O)

Bond type: Hydrogen bonds of the type OH-O between organics

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C₂H₄F₃O⁺ +  = (C₂H₄F₃O⁺ • )

By formula: C₂H₄F₃O⁺ + C₂H₃F₃O = (C₂H₄F₃O⁺ • C₂H₃F₃O)

Bond type: Hydrogen bonds of the type OH-O between organics

C₂H₄F₃O⁺ +  = (C₂H₄F₃O⁺ • )

By formula: C₂H₄F₃O⁺ + H₂O = (C₂H₄F₃O⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1982
Larson, J.W.; McMahon, T.B., Formation, Thermochemistry, and Relative Stabilities of Proton - Bound dimers of Oxygen n - Donor Bases from Ion Cyclotron Resonance Solvent - Exchange Equilibria Measurements, J. Am. Chem. Soc., 1982, 104, 23, 6255, https://doi.org/10.1021/ja00387a016 . [all data]

Cunningham, Payzant, et al., 1972
Cunningham, A.J.; Payzant, J.D.; Kebarle, P., A Kinetic Study of the Proton Hydrate H+(H2O)n Equilibria in the Gas Phase, J. Am. Chem. Soc., 1972, 94, 22, 7627, https://doi.org/10.1021/ja00777a003 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Notes

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• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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