2,6-Di-tert-butylpyridine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C13H22N+ + Pyridine, 2,6-bis(1,1-dimethylethyl)- = (C13H22N+ • Pyridine, 2,6-bis(1,1-dimethylethyl)-)

By formula: C13H22N+ + C13H21N = (C13H22N+ • C13H21N)

Quantity Value Units Method Reference Comment
Δr23.kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>
Quantity Value Units Method Reference Comment
Δr60.cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5313.PHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>

C13H22N+ + Water = (C13H22N+ • Water)

By formula: C13H22N+ + H2O = (C13H22N+ • H2O)

Bond type: Hydrogen bonds with steric hindrance in positive ions

Quantity Value Units Method Reference Comment
Δr12.5kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase
Quantity Value Units Method Reference Comment
Δr41.cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C13H22N+ + Pyridine, 2,6-bis(1,1-dimethylethyl)- = (C13H22N+ • Pyridine, 2,6-bis(1,1-dimethylethyl)-)

By formula: C13H22N+ + C13H21N = (C13H22N+ • C13H21N)

Quantity Value Units Method Reference Comment
Δr23.kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>
Quantity Value Units Method Reference Comment
Δr60.cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5313.PHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), DG<, ΔrS>

C13H22N+ + Water = (C13H22N+ • Water)

By formula: C13H22N+ + H2O = (C13H22N+ • H2O)

Bond type: Hydrogen bonds with steric hindrance in positive ions

Quantity Value Units Method Reference Comment
Δr12.5kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase
Quantity Value Units Method Reference Comment
Δr41.cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner M. and Sieck, 1983
Meot-Ner M.; Sieck, L.W., The Ionic Hydrogen Bond. 1. Sterically Hindered Bonds. Solvation and Clustering of Sterically Hindered Amines and Pyridines, J. Am. Chem. Soc., 1983, 105, 10, 2956, https://doi.org/10.1021/ja00348a005 . [all data]


Notes

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