ClFCH anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CHClF- + Hydrogen cation = Methane, chlorofluoro-

By formula: CHClF- + H+ = CH2ClF

Quantity Value Units Method Reference Comment
Δr1614.8 ± 4.0kJ/molG+TSPoutsma, Paulino, et al., 1997gas phase; Relative to MeOH at ΔGacid=375.1
Quantity Value Units Method Reference Comment
Δr1576.1 ± 1.3kJ/molIMREPoutsma, Paulino, et al., 1997gas phase; Relative to MeOH at ΔGacid=375.1

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CHClF- + Hydrogen cation = Methane, chlorofluoro-

By formula: CHClF- + H+ = CH2ClF

Quantity Value Units Method Reference Comment
Δr1614.8 ± 4.0kJ/molG+TSPoutsma, Paulino, et al., 1997gas phase; Relative to MeOH at ΔGacid=375.1
Quantity Value Units Method Reference Comment
Δr1576.1 ± 1.3kJ/molIMREPoutsma, Paulino, et al., 1997gas phase; Relative to MeOH at ΔGacid=375.1

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Poutsma, Paulino, et al., 1997
Poutsma, J.C.; Paulino, J.A.; Squires, R.R., Absolute Heats of Formation of CHCl, CHF, and CClF. A Gas-Phase Experimental and G2 Theoretical Study., J. Phys. Chem. A, 1997, 101, 29, 5327, https://doi.org/10.1021/jp970778f . [all data]


Notes

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