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MeOH..pMe-C6H4CðC anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas2.2 ± 3.2kcal/molTherChabinyc and Brauman, 1999Anchored to MeOH «DELTA»Gacid=375.2

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C9H7- + Methyl Alcohol = C10H11O-

By formula: C9H7- + CH4O = C10H11O-

Quantity Value Units Method Reference Comment
Deltar21.6 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2
Quantity Value Units Method Reference Comment
Deltar10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase
Deltar11.1 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C9H7- + Methyl Alcohol = C10H11O-

By formula: C9H7- + CH4O = C10H11O-

Quantity Value Units Method Reference Comment
Deltar21.6 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2
Quantity Value Units Method Reference Comment
Deltar10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase
Deltar11.1 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chabinyc and Brauman, 1999
Chabinyc, M.L.; Brauman, J.I., Hydrogen bond strength and acidity. Structural and energetic correlations for acetylides and alcohols, J. Phys. Chem. A, 1999, 103, 46, 9163-9166, https://doi.org/10.1021/jp992852v . [all data]

Mustanir, Matsuoka, et al., 2006
Mustanir; Matsuoka, M.; Mishima, M.; Koch, H., Stability of complexes of phenylacetylides and benzyl alkoxides with methanol in the gas phase. Acid-base correlation in the ionic hydrogen-bond strength, Bull. Chem. Soc. Japan, 2006, 79, 7, 1118-1125, https://doi.org/10.1246/bcsj.79.1118 . [all data]


Notes

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