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m-tBu-benzoate anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.79 ± 0.16D-EAKulhanek, Decouzon, et al., 1999 

Protonation reactions

C11H13O2- + Hydrogen cation = 3-Tert-butylbenzoic acid

By formula: C11H13O2- + H+ = C11H14O2

Quantity Value Units Method Reference Comment
Deltar1419. ± 9.2kJ/molG+TSKulhanek, Decouzon, et al., 1999gas phase
Quantity Value Units Method Reference Comment
Deltar1390. ± 8.4kJ/molIMREKulhanek, Decouzon, et al., 1999gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kulhanek, Decouzon, et al., 1999
Kulhanek, J.; Decouzon, M.; Gal, J.F.; Maria, P.C.; Fiedler, P.; Jimenez, P.; Roux, M.V.; Exner, O., Steric effects and steric hindrance to resonance in tert-butylbenzoic acids in the gas phase and in solution, Eur. J. Org., 1999, Chem., 7, 1589-1594, https://doi.org/10.1002/(SICI)1099-0690(199907)1999:7<1589::AID-EJOC1589>3.0.CO;2-S . [all data]


Notes

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