(MeOH)2..MeO anion
- Formula: C3H11O3-
- Molecular weight: 95.1182
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -742.2 ± 5.0 | kJ/mol | Ther | Meot-Ner(Mautner), 1986 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C3H11O3- + + 2
= C3H13O4-
By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 26.8 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
C2H7O2- + 2 = C3H11O3-
By formula: C2H7O2- + 2CH4O = C3H11O3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89.5 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 54.8 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
C3H11O3- + 3 = C4H15O4-
By formula: C3H11O3- + 3CH4O = C4H15O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.8 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 30.1 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
C2H7O2- + 2 = C3H11O3-
By formula: C2H7O2- + 2CH4O = C3H11O3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89.5 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 54.8 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
C3H11O3- + 3 = C4H15O4-
By formula: C3H11O3- + 3CH4O = C4H15O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.8 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 30.1 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
C3H11O3- + + 2
= C3H13O4-
By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 ± 4.2 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 26.8 ± 2.1 | kJ/mol | TDAs | Meot-Ner(Mautner), 1986 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M.,
Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol,
J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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