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(MeOH)2..MeO anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

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Clustering reactions

C2H7O2- + 2Methyl Alcohol = C3H11O3-

By formula: C2H7O2- + 2CH4O = C3H11O3-

QuantityValueUnitsMethodReferenceComment
Deltar89.5 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
QuantityValueUnitsMethodReferenceComment
Deltar54.8 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

C3H11O3- + 3Methyl Alcohol = C4H15O4-

By formula: C3H11O3- + 3CH4O = C4H15O4-

QuantityValueUnitsMethodReferenceComment
Deltar62.8 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
QuantityValueUnitsMethodReferenceComment
Deltar30.1 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

C3H11O3- + Water + 2Methyl Alcohol = C3H13O4-

By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-

QuantityValueUnitsMethodReferenceComment
Deltar57.7 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
QuantityValueUnitsMethodReferenceComment
Deltar26.8 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189. [doi:10.1021/ja00280a014] [all data]


Notes

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