(MeOH)2..MeO anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-742.2 ± 5.0kJ/molTherMeot-Ner(Mautner), 1986 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H11O3- + Water + 2Methyl Alcohol = C3H13O4-

By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-

Quantity Value Units Method Reference Comment
Δr57.7 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Δr26.8 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

C2H7O2- + 2Methyl Alcohol = C3H11O3-

By formula: C2H7O2- + 2CH4O = C3H11O3-

Quantity Value Units Method Reference Comment
Δr89.5 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Δr54.8 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

C3H11O3- + 3Methyl Alcohol = C4H15O4-

By formula: C3H11O3- + 3CH4O = C4H15O4-

Quantity Value Units Method Reference Comment
Δr62.8 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Δr30.1 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]


Notes

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