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SmCl3..Cl anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Deltar289. ± 16.kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention
Deltar362. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl4Sm- + samarium dichloride = Cl6Sm2-

By formula: Cl4Sm- + samarium dichloride = Cl6Sm2-

Quantity Value Units Method Reference Comment
Deltar230. ± 9.2kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; Analyzed as SmCl2..SmCl4-; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khasanshin, Pogrebnoi, et al., 1998
Khasanshin, I.V.; Pogrebnoi, A.M.; Kudin, L.S.; Kuznetsov, A.Y.; Butman, M.F., The Neutral and Ionic Components of Saturated Vapor of Samarium Dichloride: The Thermochemical Characteristics of Gaseous Molecules and Ions, High Temp., 1998, 36, 687-694. [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]


Notes

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