SmCl3..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1325. ± 10.kJ/molTherKhasanshin, Pogrebnoi, et al., 1998value altered from reference due to conversion from electron convention to ion convention
Δfgas-1309. ± 21.kJ/molTherKudin, Vorob'ev, et al., 2007value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Δr289. ± 16.kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr362. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl4Sm- + samarium dichloride = Cl6Sm2-

By formula: Cl4Sm- + samarium dichloride = Cl6Sm2-

Quantity Value Units Method Reference Comment
Δr230. ± 9.2kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; Analyzed as SmCl2..SmCl4-; value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Δr289. ± 16.kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr362. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl4Sm- + samarium dichloride = Cl6Sm2-

By formula: Cl4Sm- + samarium dichloride = Cl6Sm2-

Quantity Value Units Method Reference Comment
Δr230. ± 9.2kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; Analyzed as SmCl2..SmCl4-; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khasanshin, Pogrebnoi, et al., 1998
Khasanshin, I.V.; Pogrebnoi, A.M.; Kudin, L.S.; Kuznetsov, A.Y.; Butman, M.F., The Neutral and Ionic Components of Saturated Vapor of Samarium Dichloride: The Thermochemical Characteristics of Gaseous Molecules and Ions, High Temp., 1998, 36, 687-694. [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]


Notes

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