Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

H3B-P(Me)2CH2 anion


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.60 ± 0.10IMRBRen, Workman, et al., 1998 

Protonation reactions

C3H11BP- + Hydrogen cation = p,p,p-Trimethylphosphine-borane

By formula: C3H11BP- + H+ = C3H12BP

Quantity Value Units Method Reference Comment
Deltar1567. ± 8.8kJ/molG+TSRen, Workman, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Deltar1529. ± 8.4kJ/molIMRBRen, Workman, et al., 1998gas phase

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, References