O2C(CH2)3CO2 dianion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C5H6O4-2 • Water) + Water = (C5H6O4-2 • 2Water)

By formula: (C5H6O4-2 • H2O) + H2O = (C5H6O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr12.7 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.

C5H6O4-2 + Water = (C5H6O4-2 • Water)

By formula: C5H6O4-2 + H2O = (C5H6O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr8.1 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.

C5H6O4-2 + Hydrogen cation = C5H7O4-2

By formula: C5H6O4-2 + H+ = C5H7O4-2

Quantity Value Units Method Reference Comment
Δr413.9 ± 3.7kcal/molD-EADing, Wang, et al., 1998gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.550 ± 0.090LPESDing, Wang, et al., 1998 

Protonation reactions

C5H6O4-2 + Hydrogen cation = C5H7O4-2

By formula: C5H6O4-2 + H+ = C5H7O4-2

Quantity Value Units Method Reference Comment
Δr413.9 ± 3.7kcal/molD-EADing, Wang, et al., 1998gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C5H6O4-2 + Hydrogen cation = C5H7O4-2

By formula: C5H6O4-2 + H+ = C5H7O4-2

Quantity Value Units Method Reference Comment
Δr413.9 ± 3.7kcal/molD-EADing, Wang, et al., 1998gas phase

C5H6O4-2 + Water = (C5H6O4-2 • Water)

By formula: C5H6O4-2 + H2O = (C5H6O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr8.1 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.

(C5H6O4-2 • Water) + Water = (C5H6O4-2 • 2Water)

By formula: (C5H6O4-2 • H2O) + H2O = (C5H6O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr12.7 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ding, Wang, et al., 1998
Ding, C.F.; Wang, X.B.; Wang, L.S., Photoelectron spectroscopy of doubly charged anions: Intramolecular Coulomb repulsion and solvent stabilization, J. Phys. Chem. A, 1998, 102, 45, 8633-8636, https://doi.org/10.1021/jp982698x . [all data]


Notes

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