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(CS2)2 radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.65001LPESMabbs, Surber, et al., 2003Vertical Detachment Energy. From CS2 solvated CS2-. See also Maeyama, Oikawa, et al., 1998. See Matsuyama and Nagata, 2008 for exptl. structure
2.69998LPESMabbs, Surber, et al., 2003Vertical Detachment Energy. From covalent bound dimer anion
1.650 ± 0.020LPESTsukuda, Hirose, et al., 1997EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mabbs, Surber, et al., 2003
Mabbs, R.; Surber, E.; Sanov, A., An experimental manifestation of distinct electronic-structural properties of covalent dimer anions of CO2 and CS2, Chem. Phys., 2003, 381, 479-485. [all data]

Maeyama, Oikawa, et al., 1998
Maeyama, T.; Oikawa, T.; Tsumura, T.; Mikami, N., Photodestruction spectroscopy of carbon disulfide cluster anions (CS2)(n)(-) n=1-4: Evidence for the dimer core structure and competitive reactions of the dimer anion, J. Chem. Phys., 1998, 108, 4, 1368-1376, https://doi.org/10.1063/1.475510 . [all data]

Matsuyama and Nagata, 2008
Matsuyama, Y.; Nagata, T., Structures of C2S4- Molecular Anion: Photoelectron Spectroscopy and Theoretical Calculations, Chem. Phys. Lett., 2008, 457, 1-3, 31-35., https://doi.org/10.1016/j.cplett.2008.03.068 . [all data]

Tsukuda, Hirose, et al., 1997
Tsukuda, T.; Hirose, T.; Nagata, T., Negative-ion photoelectron spectroscopy of (CS2)(n)(-): coexistence of electronic isomers, Chem. Phys. Lett., 1997, 279, 3-4, 179-184, https://doi.org/10.1016/S0009-2614(97)01021-X . [all data]


Notes

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