1,2,4,5-tetrafluorophenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C6HF4- + Hydrogen cation = Benzene, 1,2,4,5-tetrafluoro-

By formula: C6HF4- + H+ = C6H2F4

Quantity Value Units Method Reference Comment
Δr1513. ± 8.8kJ/molG+TSBuker, Nibbering, et al., 1997gas phase
Quantity Value Units Method Reference Comment
Δr1478. ± 8.4kJ/molIMREBuker, Nibbering, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C6HF4- + Hydrogen cation = Benzene, 1,2,4,5-tetrafluoro-

By formula: C6HF4- + H+ = C6H2F4

Quantity Value Units Method Reference Comment
Δr1513. ± 8.8kJ/molG+TSBuker, Nibbering, et al., 1997gas phase
Quantity Value Units Method Reference Comment
Δr1478. ± 8.4kJ/molIMREBuker, Nibbering, et al., 1997gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buker, Nibbering, et al., 1997
Buker, H.H.; Nibbering, N.M.M.; Espinosa, D.; Mongin, F.; Schlosser, M., Additivity of substituent effects in the fluoroarene series: Equilibrium acidity in the gas phase and deprotonation rates in ethereal solution, Tetrahed. Lett., 1997, 38, 49, 8519-8522, https://doi.org/10.1016/S0040-4039(97)10303-3 . [all data]


Notes

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