1,2,3-trifluorophenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C6H2F3- + Hydrogen cation = 1,2,3-Trifluorobenzene

By formula: C6H2F3- + H+ = C6H3F3

Quantity Value Units Method Reference Comment
Δr375.5 ± 2.1kcal/molG+TSBuker, Nibbering, et al., 1997gas phase
Quantity Value Units Method Reference Comment
Δr367.3 ± 2.0kcal/molIMREBuker, Nibbering, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C6H2F3- + Hydrogen cation = 1,2,3-Trifluorobenzene

By formula: C6H2F3- + H+ = C6H3F3

Quantity Value Units Method Reference Comment
Δr375.5 ± 2.1kcal/molG+TSBuker, Nibbering, et al., 1997gas phase
Quantity Value Units Method Reference Comment
Δr367.3 ± 2.0kcal/molIMREBuker, Nibbering, et al., 1997gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buker, Nibbering, et al., 1997
Buker, H.H.; Nibbering, N.M.M.; Espinosa, D.; Mongin, F.; Schlosser, M., Additivity of substituent effects in the fluoroarene series: Equilibrium acidity in the gas phase and deprotonation rates in ethereal solution, Tetrahed. Lett., 1997, 38, 49, 8519-8522, https://doi.org/10.1016/S0040-4039(97)10303-3 . [all data]


Notes

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