CO..Pt3(CO)2 radical anion
- Formula: C3O3Pt3-
- Molecular weight: 669.283
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -210. ± 71. | kJ/mol | Ther | Grushow and Ervin, 1997 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C2O2Pt3- + = C3O3Pt3-
By formula: C2O2Pt3- + CO = C3O3Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 22. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
ΔrH° | 206. ± 14. | kJ/mol | PDis | Shi, Spasov, et al., 2001 | gas phase |
C3O3Pt3- + = C4O4Pt3-
By formula: C3O3Pt3- + CO = C4O4Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 13. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
C2O2Pt3- + = C3O3Pt3-
By formula: C2O2Pt3- + CO = C3O3Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 22. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
ΔrH° | 206. ± 14. | kJ/mol | PDis | Shi, Spasov, et al., 2001 | gas phase |
C3O3Pt3- + = C4O4Pt3-
By formula: C3O3Pt3- + CO = C4O4Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 13. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Grushow and Ervin, 1997
Grushow, A.; Ervin, K.M.,
Ligand and Metal Binding Energies in Platinum Carbonyl Cluster Anions: Collision Induced Dissociation of PtM- and Ptm(CO)n-,
J. Chem. Phys., 1997, 106, 23, 9580, https://doi.org/10.1063/1.474116
. [all data]
Shi, Spasov, et al., 2001
Shi, Y.; Spasov, V.A.; Ervin, K.M.,
Photodesorption of carbonyl from Pt-3(CO)(n)(-) (n=1-6),
Int. J. Mass Spectrom., 2001, 204, 1-3, 197-208, https://doi.org/10.1016/S1387-3806(00)00364-X
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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