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CO..Pt3CO radical anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2O2Pt3- + Carbon monoxide = C3O3Pt3-

By formula: C2O2Pt3- + CO = C3O3Pt3-

Quantity Value Units Method Reference Comment
Deltar220. ± 22.kJ/molN/AGrushow and Ervin, 1997gas phase
Deltar206. ± 14.kJ/molPDisShi, Spasov, et al., 2001gas phase

COPt3- + Carbon monoxide = C2O2Pt3-

By formula: COPt3- + CO = C2O2Pt3-

Quantity Value Units Method Reference Comment
Deltar220. ± 50.kJ/molN/AGrushow and Ervin, 1997gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grushow and Ervin, 1997
Grushow, A.; Ervin, K.M., Ligand and Metal Binding Energies in Platinum Carbonyl Cluster Anions: Collision Induced Dissociation of PtM- and Ptm(CO)n-, J. Chem. Phys., 1997, 106, 23, 9580, https://doi.org/10.1063/1.474116 . [all data]

Shi, Spasov, et al., 2001
Shi, Y.; Spasov, V.A.; Ervin, K.M., Photodesorption of carbonyl from Pt-3(CO)(n)(-) (n=1-6), Int. J. Mass Spectrom., 2001, 204, 1-3, 197-208, https://doi.org/10.1016/S1387-3806(00)00364-X . [all data]


Notes

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