V15 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.49 ± 0.15LPESPramann, Koyasu, et al., 2002Vertical Detachment Energy: 1.71±0.08 eV
1.63 ± 0.10LPESIseda, Nishio, et al., 1997EA set as 5% threshold for first peak.
1.720 ± 0.080LPESWu, Desai, et al., 1996 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pramann, Koyasu, et al., 2002
Pramann, A.; Koyasu, K.; Nakajima, A.; Kaya, K., Anion photoelectron spectroscopy of VnOm- (n=4-15; m=0-2), J. Chem. Phys., 2002, 116, 15, 6521-6528, https://doi.org/10.1063/1.1461824 . [all data]

Iseda, Nishio, et al., 1997
Iseda, M.; Nishio, T.; Han, S.Y.; Yoshida, H.; Terasaki, A.; Kondow, T., Electronic Structure of Vanadium Cluster Anions as Studied by Photoelectron Spectroscopy, J. Chem. Phys., 1997, 106, 6, 2182, https://doi.org/10.1063/1.473785 . [all data]

Wu, Desai, et al., 1996
Wu, H.; Desai, S.R.; Wang, L., Evolution of the Electronic Structure of Small Vanadium Clusters from Molecular to Bulklike, Phys. Rev. Lett. (1996), 1996, 77, 12, 2436, https://doi.org/10.1103/PhysRevLett.77.2436 . [all data]


Notes

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