LuCl3..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1193.4kJ/molTherPogrebnoi, Kudion, et al., 1997EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention
Δfgas-1292. ± 12.kJ/molTherKudin, Vorob'ev, et al., 2007value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cl4Lu- + Cl3Lu = Cl7Lu2-

By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-

Quantity Value Units Method Reference Comment
Δr207. ± 10.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr256. ± 33.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cl4Lu- + Cl3Lu = Cl7Lu2-

By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-

Quantity Value Units Method Reference Comment
Δr207. ± 10.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr256. ± 33.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F., Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride, Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D . [all data]

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]


Notes

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