LuCl3..Cl anion
- Formula: Cl4Lu-
- Molecular weight: 316.779
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 207. ± 10. | kJ/mol | TDAs | Pogrebnoi, Kudion, et al., 1997 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 256. ± 33. | kJ/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F.,
Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride,
Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D
. [all data]
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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