LuCl3..Cl anion
- Formula: Cl4Lu-
- Molecular weight: 316.779
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -1193.4 | kJ/mol | Ther | Pogrebnoi, Kudion, et al., 1997 | EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention |
| ΔfH°gas | -1292. ± 12. | kJ/mol | Ther | Kudin, Vorob'ev, et al., 2007 | value altered from reference due to conversion from electron convention to ion convention |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 207. ± 10. | kJ/mol | TDAs | Pogrebnoi, Kudion, et al., 1997 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 256. ± 33. | kJ/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Gas phase thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F.,
Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride,
Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D
. [all data]
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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