MeSCHCN anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4NS- + Hydrogen cation = (Methylthio)-acetonitrile

By formula: C3H4NS- + H+ = C3H5NS

Quantity Value Units Method Reference Comment
Δr1496. ± 10.kJ/molG+TSBorn, Ingemann, et al., 1996gas phase; Acidity >CF3CH2OH, comparable to MeNO2
Quantity Value Units Method Reference Comment
Δr1464. ± 8.4kJ/molIMRBBorn, Ingemann, et al., 1996gas phase; Acidity >CF3CH2OH, comparable to MeNO2

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C3H4NS- + Hydrogen cation = (Methylthio)-acetonitrile

By formula: C3H4NS- + H+ = C3H5NS

Quantity Value Units Method Reference Comment
Δr1496. ± 10.kJ/molG+TSBorn, Ingemann, et al., 1996gas phase; Acidity >CF3CH2OH, comparable to MeNO2
Quantity Value Units Method Reference Comment
Δr1464. ± 8.4kJ/molIMRBBorn, Ingemann, et al., 1996gas phase; Acidity >CF3CH2OH, comparable to MeNO2

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Born, Ingemann, et al., 1996
Born, M.; Ingemann, S.; Nibbering, N.M.M., Experimental Determination of the Enthalpies of Formation of Formyl Cyanide and Thioformyl Cyanide in the Gas Phase, J. Phys. Chem., 1996, 100, 44, 17662, https://doi.org/10.1021/jp9609141 . [all data]


Notes

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