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(H2O)3..HCO3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-1655.7kJ/molTherKeesee, Lee, et al., 1979 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH5O5- + 3Water = CH7O6-

By formula: CH5O5- + 3H2O = CH7O6-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar19. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase

CH7O6- + 4Water = CH9O7-

By formula: CH7O6- + 4H2O = CH9O7-

Quantity Value Units Method Reference Comment
Deltar56.1 ± 3.8kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH5O5- + 3Water = CH7O6-

By formula: CH5O5- + 3H2O = CH7O6-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar19. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase

CH7O6- + 4Water = CH9O7-

By formula: CH7O6- + 4H2O = CH9O7-

Quantity Value Units Method Reference Comment
Deltar56.1 ± 3.8kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]


Notes

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