Vanadium pentafluoride
- Formula: F5V
- Molecular weight: 145.9335
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: D3h Symmetry Number σ = 6
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a1' | 1 | VF3 s-str | 718 | B | 718 VS | gas | ||||
| a1' | 2 | VF2 s-str | 608 | B | 608 M | gas | ||||
| a2 | 3 | VF2 a-str | 784 | B | 784 S | gas | ||||
| a2 | 4 | VF3 op-deform | 331 | B | 331 W | gas | ||||
| e' | 5 | VF3 d-str | 810 | C | 810 M | gas | 812 W | gas | ||
| e' | 6 | VF3 d-deform | 282 | C | 282 M | gas | 286 VW | gas | ||
| e' | 7 | VF bend | 110 | D | 109.5 M | gas | 99 W | gas | ||
| e | 8 | VF bend | 336 | B | 336 M | gas | ||||
Source: Shimanouchi, 1972
Notes
| VS | Very strong |
| S | Strong |
| M | Medium |
| W | Weak |
| VW | Very weak |
| B | 1~3 cm-1 uncertainty |
| C | 3~6 cm-1 uncertainty |
| D | 6~15 cm-1 uncertainty |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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