Thiophosphoryl dichlorofluoride
- Formula: Cl2FPS
- Molecular weight: 152.943
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: Cs Symmetry Number σ = 1
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a' | 1 | PF str | 912 | B | 912 VS | gas | 902 p | liq. | ||
| a' | 2 | PS str | 753 | B | 753 VS | gas | 737 p | liq. | ||
| a' | 3 | PCl2 s-str | 478 | B | 478 S | gas | 474 p | liq. | ||
| a' | 4 | PF bend | 331 | B | 331 M | gas | 327 dp | liq. | ||
| a' | 5 | PS ip-bend | 268 | B | 268 M | gas | 267 p | liq. | ||
| a' | 6 | PCl2 scis | 192 | D | 192 W | gas | 193 dp | liq. | OV(ν9) | |
| a | 7 | PCl2 a-str | 575 | C | 575 S | gas | 567 dp | liq. | ||
| a | 8 | PS op-bend | 319 | B | 319 M | gas | 317 dp | liq. | ||
| a | 9 | PCl2 rock | 192 | D | 192 W | gas | 193 dp | liq. | OV(ν6) | |
Source: Shimanouchi, 1972
Notes
| VS | Very strong |
| S | Strong |
| M | Medium |
| W | Weak |
| p | Polarized |
| dp | Depolarized |
| OV | Overlapped by band indicated in parentheses. |
| B | 1~3 cm-1 uncertainty |
| C | 3~6 cm-1 uncertainty |
| D | 6~15 cm-1 uncertainty |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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