Tetracyanoethylene anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas400. ± 20.kJ/molR-EAChowdhury and Kebarle, 1986ΔGea(423 K) = -73.0 kcal/mol; ΔSea (estimated) = 0. eu.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Tetracyanoethylene anion = C6H2N4O-

By formula: C6N4- = C6H2N4O-

Quantity Value Units Method Reference Comment
Δr34. ± 4.6kJ/molN/AKhuseynov, Fontana, et al., 2012gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Tetracyanoethylene anion = C6H2N4O-

By formula: C6N4- = C6H2N4O-

Quantity Value Units Method Reference Comment
Δr34. ± 4.6kJ/molN/AKhuseynov, Fontana, et al., 2012gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Electron affinities of di- and tetracyanoethylene and cyanobenzenes based on measurements of gas-phase electron transfer equilibria, J. Am. Chem. Soc., 1986, 108, 5453. [all data]

Khuseynov, Fontana, et al., 2012
Khuseynov, D.; Fontana, M.T.; Sanov, A., Photoelectron spectroscopy and photochemistry of tetracyanoethylene radical anion in the gas phase, Chem. Phys. Lett., 2012, 550, 15-18, https://doi.org/10.1016/j.cplett.2012.08.035 . [all data]


Notes

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