Nitromethane anion
- Formula: CH3NO2-
- Molecular weight: 61.0406
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -90.92 ± 0.75 | kJ/mol | R-EA | Adams, Schneider, et al., 2009 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(CH3NO2- • ) +
= (CH3NO2- • 2
)
By formula: (CH3NO2- • CH3NO2) + CH3NO2 = (CH3NO2- • 2CH3NO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 50. ± 150. | kJ/mol | N/A | Compton, Carman Jr., et al., 1996 | gas phase; shift in electron detachment from less solvated ion |
| ΔrH° | 53.6 ± 1.3 | kJ/mol | TDAs | Wincel, 2003 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 24.7 | kJ/mol | TDAs | Wincel, 2003 | gas phase |
CH3NO2- + = (CH3NO2- •
)
By formula: CH3NO2- + CH3NO2 = (CH3NO2- • CH3NO2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 63.60 ± 0.84 | kJ/mol | N/A | Compton, Carman Jr., et al., 1996 | gas phase; Shift in electron detachment from non-solvated ion |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adams, Schneider, et al., 2009
Adams, C.L.; Schneider, H.; Ervin, K.M.; Weber, J.M.,
Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state,
J. Chem. Phys., 2009, 130, 7, 074307, https://doi.org/10.1063/1.3076892
. [all data]
Compton, Carman Jr., et al., 1996
Compton, R.N.; Carman Jr.; Desfrancois, C.; Abdoul-Carmine, H.; Schermann, J.P.; Hendricks, J.H.,
On the binding of Electrons to Nitromethane: Dipole and Valence Bound Anions,
J. Chem. Phys., 1996, 105, 9, 3472, https://doi.org/10.1063/1.472993
. [all data]
Wincel, 2003
Wincel, H.,
Gas-phase Solvation of Cl-, NO2-, CH2NO2-, CH3NO2-, and CH3NO4- by CH3NO2,
Int. J. Mass Spectrom., 2003, 226, 3, 341-353, https://doi.org/10.1016/S1387-3806(03)00066-6
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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