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(CO2)6..CO3 radical anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

C6O13- + 6Carbon dioxide = C7O15-

By formula: C6O13- + 6CO2 = C7O15-

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar-1.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase

C7O15- + 7Carbon dioxide = C8O17-

By formula: C7O15- + 7CO2 = C8O17-

Quantity Value Units Method Reference Comment
Deltar4.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; Estimated entropy; single temperature measurement
Quantity Value Units Method Reference Comment
Deltar-2.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; Estimated entropy; single temperature measurement

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]


Notes

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