(CO2)6..CO3 radical anion
- Formula: C7O15-
- Molecular weight: 324.0664
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -716.55 | kcal/mol | Ther | Hiraoka and Yamabe, 1992 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C7O15- + 7 = C8O17-
By formula: C7O15- + 7CO2 = C8O17-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 4.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; Estimated entropy; single temperature measurement |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -2.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase; Estimated entropy; single temperature measurement |
C6O13- + 6 = C7O15-
By formula: C6O13- + 6CO2 = C7O15-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 4.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | -1.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S.,
Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n,
J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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