(CO2)4..CO3 radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-2171.4kJ/molTherHiraoka and Yamabe, 1992 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

C4O9- + 4Carbon dioxide = C5O11-

By formula: C4O9- + 4CO2 = C5O11-

Quantity Value Units Method Reference Comment
Δr22. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Δr-6.3 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase

C5O11- + 5Carbon dioxide = C6O13-

By formula: C5O11- + 5CO2 = C6O13-

Quantity Value Units Method Reference Comment
Δr20. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Δr-7.5 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]


Notes

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