HOS anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HOS- + Hydrogen cation = H2OS

By formula: HOS- + H+ = H2OS

Quantity Value Units Method Reference Comment
Δr1481. ± 15.kJ/molG+TSOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH
Quantity Value Units Method Reference Comment
Δr1452. ± 13.kJ/molIMRBOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.655 ± 0.040LPESOhair, Depuy, et al., 1993footnote: Unpublished results of Gunion, Polak, Lineberger, 1992. Lineberger (private communication).

Protonation reactions

HOS- + Hydrogen cation = H2OS

By formula: HOS- + H+ = H2OS

Quantity Value Units Method Reference Comment
Δr1481. ± 15.kJ/molG+TSOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH
Quantity Value Units Method Reference Comment
Δr1452. ± 13.kJ/molIMRBOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohair, Depuy, et al., 1993
Ohair, R.A.J.; Depuy, C.H.; Bierbaum, V.M., Gas-Phase Chemistry and Thermochemistry of the Hydroxysulfide Anion, HOS-, J. Phys. Chem., 1993, 97, 30, 7955, https://doi.org/10.1021/j100132a026 . [all data]


Notes

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