(MeO)2BO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H6BO3- + Hydrogen cation = C2H7BO3

By formula: C2H6BO3- + H+ = C2H7BO3

Quantity Value Units Method Reference Comment
Δr360.2 ± 4.6kcal/molG+TSKiplinger, Crowder, et al., 1994gas phase; between tBuCH=NOH, pyrrole. Stein, Rikkers, et al. is wrong on GpAd for (MeO)2BOH
Quantity Value Units Method Reference Comment
Δr353.4 ± 4.5kcal/molIMRBKiplinger, Crowder, et al., 1994gas phase; between tBuCH=NOH, pyrrole. Stein, Rikkers, et al. is wrong on GpAd for (MeO)2BOH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H6BO3- + Hydrogen cation = C2H7BO3

By formula: C2H6BO3- + H+ = C2H7BO3

Quantity Value Units Method Reference Comment
Δr360.2 ± 4.6kcal/molG+TSKiplinger, Crowder, et al., 1994gas phase; between tBuCH=NOH, pyrrole. Stein, Rikkers, et al. is wrong on GpAd for (MeO)2BOH
Quantity Value Units Method Reference Comment
Δr353.4 ± 4.5kcal/molIMRBKiplinger, Crowder, et al., 1994gas phase; between tBuCH=NOH, pyrrole. Stein, Rikkers, et al. is wrong on GpAd for (MeO)2BOH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiplinger, Crowder, et al., 1994
Kiplinger, J.P.; Crowder, C.A.; Sorensen, D.N.; Bartmess, J.E., Gas-Phase Ion-Molecule Chemistry of Borate and Boronate Esters, J. Am. Soc. Mass Spectrom., 1994, 5, 3, 169, https://doi.org/10.1016/1044-0305(94)85030-5 . [all data]

Stein, Rikkers, et al.
Stein, S.E.; Rikkers, J.M.; Brown, R.L., NIST Structure anmd Properties Database and Estimation Program, Ver. 1.1, NIST Standard Reference Database 25. [all data]


Notes

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