quadricyclan-1-ide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7H7- + Hydrogen cation = Tetracyclo[3.2.0.0(2,7).0(4,6)]heptane

By formula: C7H7- + H+ = C7H8

Quantity Value Units Method Reference Comment
Δr1685.7 ± 3.8kJ/molG+TSLee, DePuy, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr1651.4 ± 3.3kJ/molIMRELee, DePuy, et al., 1996gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.9620 ± 0.0060LPESGunion, Karney, et al., 1996Assignment of 1- and 2- isomers uncertain.

Protonation reactions

C7H7- + Hydrogen cation = Tetracyclo[3.2.0.0(2,7).0(4,6)]heptane

By formula: C7H7- + H+ = C7H8

Quantity Value Units Method Reference Comment
Δr1685.7 ± 3.8kJ/molG+TSLee, DePuy, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr1651.4 ± 3.3kJ/molIMRELee, DePuy, et al., 1996gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee, DePuy, et al., 1996
Lee, H.S.; DePuy, C.H.; Bierbaum, V.M., Reactivity and Thermochemistry of Quadricyclane in the Gas Phase, J. Am. Chem. Soc., 1996, 118, 21, 5068, https://doi.org/10.1021/ja9540278 . [all data]

Gunion, Karney, et al., 1996
Gunion, R.F.; Karney, W.; Wenthold, P.G.; Borden, W.T.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of Some C7H7- Isomers: Quadricyclanide, Norbornadienide, Cycloheptatrienide, and 1,6-Heptadiynide, J. Am. Chem. Soc., 1996, 118, 21, 5074, https://doi.org/10.1021/ja954026f . [all data]


Notes

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