(H2O)3..Cl anion
- Formula: ClH6O3-
- Molecular weight: 89.499
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Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| ΔfH°gas (kcal/mol) | Method | Reference | Comment |
|---|---|---|---|
| -267.43 | Ther | Hiraoka and Mizuse, 1987 | B |
| -265.13 | Ther | Dunbar, McMahon, et al., 1995 | B |
| -267.83 | Ther | Markovich, Pollack, et al., 1994 | For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
| -267.13 | Ther | Keesee and Castleman, 1980 | B |
| -267.33 | Ther | Payzant, Yamdagni, et al., 1971 | B |
| -267.33 | Ther | Arshadi, Yamdagni, et al., 1970 | B |
References
Go To: Top, Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S.,
Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH,
Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4
. [all data]
Dunbar, McMahon, et al., 1995
Dunbar, R.C.; McMahon, T.B.; Thölmann, D.; Tonner, D.S.; Salahub, D.R.; Wei, D.,
Zero-Pressure Thermal-Radiation-Induced Dissociation of Gas-Phase Cluster Ions: Comparison of Theory and Experiment for (H2O)2Cl- and (H2O)3Cl-,
J. Am. Chem. Soc., 1995, 117, 51, 12819, https://doi.org/10.1021/ja00156a020
. [all data]
Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O.,
Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters,
J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965
. [all data]
Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr.,
Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase,
Chem. Phys. Lett., 1980, 74, 139. [all data]
Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P.,
Hydration of CN-, NO2-, NO3-, and HO- in the gas phase,
Can. J. Chem., 1971, 49, 3308. [all data]
Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P.,
Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions,
J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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